group A:- unit I:- structure of atom: calculation of radius of bhor's orbit, energy of an electron in bhor's orbit...
group A:-
unit I:- structure of atom: calculation of radius of bhor's orbit, energy of an electron in bhor's orbit for H and H-like atom, Rydburg's equation, numerical problems, wave nature of electron, de-Broglie's relationship, Heisenberg's uncertainity principal, neumerical problems, diffraction experiment of Davission and germer.
Unit II:- oxidation and reduction: balancing of redox reaction by ion-electron method, reduction potential, standred reduction potential and its utility in predicting feasibility in redox reaction,
Theories of acids and bases:- Arrhenius theory, Bronsted-Lowry theory, Lewis theory,
Unit III:- nobel gases:- compound of Kr and Xe-preperation, properties and structure.
Halogens:- Oxide and oxyacids- preperation, properties and structure with special refrence to chlorine.
Unit IV:- boron family:- Electron deficient compounds-preperation, properties and structure of diborane, general study of the properties of the d-block elements with refrence to scandium series-color, megnetic and analytic properties of their compound.
Gorup B:-
Unit I:- bonding in organic molecules:- nature of covelent bond, hybridisation, implication of hybridisation on the concept of bond length, bond energy, bond angle and shapes with the following example: CH4, CH3, Benzene, RCN, C2H2. Inductive effect, conjugation, resonance and aromatricity.
Basic concept of reaction mechanism:- Electrophiles, nucleophiles, carbocations, free radicals and their stability(with simple example)
Unit II:- Stereochemistry of roganic molecules:- Elements of symmetry, Geometrical isomerism in ethylene compound- E/Z nomenclature, optical activity, optical isomers, enantiomers, diastereomers, relative and absolute configuration, R/S nomenclature.
Unit III:- introduction to alkenes and alkynes:- chemical reactivity, mechanism of hydrogenation, bromination, hydration, halohydration and Markownikoff’s rule, peroxide effect, epoxidation, ozonolysis, polymerization. Relative acidity of alkanes, alkenes and alkynes.
Unit IV:- Akylhalides and arylhalides: reactivity, SN1, SN2 process, potential energy diagrams, factors favouring SN1 and SN2 process, 1,2-elemination reaction, E1 and E2 process. Reaction of haloalkane with alcoholic KOH, Saytzaff and Hoffmann rule, Aryl halides, reactivity, comparision with alkyl halides.
Group C:-
Unit I:- Gaseous state I: postulates of kinetic theory of gases, deduction of kinetic gas equation, deviation of real gases from ideal behavior, rms, average and most probable velocities, van der waal’s equation. Critical phenomenon-PV isotherms of real gases, relation between critical constant and van der waal’s constants, the low of corresponding states.
Unit II:- gaseous state II: Maxwell distribution of molecular velocities(qualitative), collision number, mean free path, and collision diameter.
Heat capacities and their ratio, relation of specific heat ratios with atomicity of gases, Equipartion of energy, example of water and carbondioxide.
Unit III:-liquid state:- Intermolecular forces, structure of liquids(a qualitative description). Surface tension, Viscosity and their determination, effect of temperature on viscosity of liquid.
Unit IV:- solid state:- element of crystal structure, crystal lattice, unit cell, crystal system, Bravias lattices, low of rational indices, Miller indices, closed paqck structures, hcp and ccp, cordiantion number.
COMMENTS